2D Porous Polymers with sp2‐Carbon Connections and Sole sp2‐Carbon Skeletons

Accès libre Peer reviewed | |
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Version acceptée pour publication (post-print auteur) | |
Paternité - Pas d'utilisation commerciale [CC] [BY] [NC] ![]() |
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Auteurs |
Jialing Kang Senhe Huang Kaiyue Jiang Chenbao Lu Zhenying Chen Jinhui Zhu Chongqing Yang Artur Ciesielski Feng Qiu Xiaodong Zhuang |
Unité de recherche du site |
Institut de Science et d'Ingénierie Supramoléculaires - ISIS - UMR7006 |
Langue |
en |
Volume |
30 |
Numéro |
27 |
Page de début |
2000857 |
Date de première publication |
2020-04-27 |
ISSN |
1616-301X |
Titre de la source (revue, livre…) |
Advanced Functional Materials |
Résumé |
2D porous polymers with a planar architecture and high specific surface area have significant applications potential, such as for photocatalysis, electrochemical catalysis, gas storage and separation, and sensing. Such 2D porous polymers have Show more2D porous polymers with a planar architecture and high specific surface area have significant applications potential, such as for photocatalysis, electrochemical catalysis, gas storage and separation, and sensing. Such 2D porous polymers have generally been classified as 2D metal–organic frameworks, 2D covalent organic frameworks, graphitic carbon nitride, graphdiyne, and sandwich‐like porous polymer nanosheets. Among these, 2D porous polymers with sp2‐hybridized carbon (Csp2) bonding are an emerging field of interest. Compared with 2D porous polymers linked by B–O, C=N, or C≡C bonds, Csp2‐linked 2D porous polymers exhibit extended electron delocalization resulting in unique optical/electrical properties, as well as high chemical/photostability and tunable electrochemical performance. Furthermore, such 2D porous polymers are one of the best precursors for the fabrication of 2D porous carbon materials and carbon skeletons with atomically dispersed transition‐metal active sites. Herein, rational synthetic approaches for 2D porous polymers with Csp2 bonding are summarized. Their current practical photoelectric applications, including for gas separation, luminescent sensing and imaging, electrodes for batteries and supercapacitors, and photocatalysis are also discussed. Show less |
DOI | 10.1002/adfm.202000857 |
Titre abrégé de la source |
Adv. Funct. Mater. |
Type de publication |
article |
Type de publication |
ACL |
Domaine |
Chimie/Matériaux |
Unité de recherche extérieure au site |
The Meso‐Entropy Matter LabSchool of Chemistry and Chemical EngineeringShanghai Jiao Tong University 800 Dongchuan Road Shanghai 200240 China |
Fonction |
aut |
Identifiant idREF |
151349363 |
Audience |
International |
Envoyer vers HAL |
5 |
URL | https://univoak.eu/islandora/object/islandora:109591 |