Concerning restricted rotations in pyridinyl anisoles and pyridinyl phenols bearing saturated handles, and their solid state structures

Ay, Emel; Le Nouën, Didier; Chaumeil, Helene; Neuburger, Markus; Tschamber, Théophile; Jacques, Patrice

doi:10.1016/j.tetlet.2014.09.002

Concerning restricted rotations in pyridinyl anisoles and pyridinyl phenols bearing saturated handles, and their solid state structures

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AY, Emel, LE NOUËN, Didier, CHAUMEIL, Helene, NEUBURGER, Markus, TSCHAMBER, Théophile et JACQUES, Patrice, 2014. Concerning restricted rotations in pyridinyl anisoles and pyridinyl phenols bearing saturated handles, and their solid state structures. Tetrahedron Letters [en ligne]. 22 octobre 2014. [Consultésans date]. DOI 10.1016/j.tetlet.2014.09.002. Consulté de : http://www.sciencedirect.com/science/article/pii/S00404039140149191. .

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Auteurs	Emel Ay Didier Le Nouën Helene Chaumeil Markus Neuburger Théophile Tschamber Patrice Jacques
Unité de recherche du site	Laboratoire de Chimie Organique et Bioorganique - COB - EA4566 Laboratoire de Chimie Moléculaire - LCM - UMR7509 Laboratoire de Photochimie et d’Ingénierie Macromoléculaire - LPIM - EA4567
Langue	en
Volume	55
Numéro	43
Page de début	5979
Page de fin	5983
Date de première publication	2014-10-22
Date de parution	2014-10-22
ISSN	0040-4039
Titre de la source (revue, livre…)	Tetrahedron Letters
Résumé	The variable-temperature ("dynamic") NMR measurements of series of pyridinyl anisoles and pyridinyl phenols each of them bearing ortho, ortho' handles of various lengths at oxygenated ring lead to the following results: (i) at room temperature, a Show moreThe variable-temperature ("dynamic") NMR measurements of series of pyridinyl anisoles and pyridinyl phenols each of them bearing ortho, ortho' handles of various lengths at oxygenated ring lead to the following results: (i) at room temperature, a restricted rotation around the intercyclic bond of pyridinyl anisoles and pyridinyl phenol bearing short handles formed by 9-10 atoms is underscored, (ii) all handles at the former derivatives are blocked on one side of the oxygenated ring face, and (iii) handles of 11-12 atoms long at phenol rings are able to move freely. The solid-state packing indicates that all saturated chains are substantially perpendicular to the oxygenated ring. (C) 2014 Elsevier Ltd. All rights reserved. Show less
DOI	10.1016/j.tetlet.2014.09.002
Éditeur	Elsevier
URL éditeur	http://www.sciencedirect.com/science/article/pii/S0040403914014919
Titre abrégé de la source	Tetrahedron Lett.
Type de publication	journalArticle
Type de publication	ACL
Domaine	Chimie/Chimie organique
Mots-clés	chromophores nonlinear-optical properties Pyridinium phenolates Pyridinyl anisoles Pyridinyl phenols Variable-temperature NMR X-ray crystal structures
Fonction	aut crp
Identifiant idREF	122090225 061422363
Audience	International
URL	https://univoak.eu/islandora/object/islandora:27552