A nanomesh scaffold for supramolecular nanowire optoelectronic devices
| Accès libre Peer reviewed | |
|---|---|
| Version acceptée pour publication (post-print auteur) | |
| Paternité - Pas d'utilisation commerciale [CC] [BY] [NC] | |
| Auteurs |
Lei Zhang Xiaolan Zhong Egon Pavlica Songlin Li Alexander Klekachev Gvido Bratina Thomas Ebbesen Emanuele Orgiu Paolo Samori |
| Unité de recherche du site |
Institut de Science et d'Ingénierie Supramoléculaires - ISIS - UMR7006 |
| Langue |
en |
| Volume |
11 |
| Numéro |
10 |
| Page de début |
900 |
| Page de fin |
906 |
| Date de première publication |
2016-07-25 |
| ISSN |
1748-3387 |
| Titre de la source (revue, livre…) |
Nature Nanotechnology |
| Résumé |
Supramolecular organic nanowires are ideal nanostructures for optoelectronics because they exhibit both efficient exciton generation as a result of their high absorption coefficient and remarkable light sensitivity due to the low number of grain Show moreSupramolecular organic nanowires are ideal nanostructures for optoelectronics because they exhibit both efficient exciton generation as a result of their high absorption coefficient and remarkable light sensitivity due to the low number of grain boundaries and high surface-to-volume ratio. To harvest photocurrent directly from supramolecular nanowires it is necessary to wire them up with nanoelectrodes that possess different work functions. However, devising strategies that can connect multiple nanowires at the same time has been challenging. Here, we report a general approach to simultaneously integrate hundreds of supramolecular nanowires of N,N′-dioctyl-3,4,9,10-perylenedicarboximide (PTCDI-C8) in a hexagonal nanomesh scaffold with asymmetric nanoelectrodes. Optimized PTCDI-C8 nanowire photovoltaic devices exhibit a signal-to-noise ratio approaching 107, a photoresponse time as fast as 10 ns and an external quantum efficiency >55%. This nanomesh scaffold can also be used to investigate the fundamental mechanism of photoelectrical conversion in other low-dimensional semiconducting nanostructures. Show less |
| DOI | 10.1038/nnano.2016.125 |
| URL éditeur |
http://www.nature.com/nnano/journal/v11/n10/full/nnano.2016.125.html#affil-auth |
| Titre abrégé de la source |
Nature Nanotech |
| Type de publication |
ACL |
| Domaine |
Chimie/Matériaux |
| Mots-clés |
Electronic properties and materials |
| Unité de recherche extérieure au site |
Laboratory for Organic Matter Physics, University of Nova Gorica, Vipavska 13, SI-5000 Nova Gorica, Slovenia |
| Fonction |
aut |
| Identifiant idREF |
185523617 086037536 19105190X 109288335 |
| Audience |
International |
| URL | https://univoak.eu/islandora/object/islandora:51668 |