Coherent coupling of molecular resonators with a microcavity mode
| Accès libre Peer reviewed | |
|---|---|
| Version finale publiée (post-print éditeur) | |
| Paternité [CC] [BY] | |
| Auteurs |
Atef Shalabney Jino George James Andell Hutchison Guido Pupillo Cyriaque Genet Thomas Ebbesen |
| Unité de recherche du site |
Institut de Science et d'Ingénierie Supramoléculaires - ISIS - UMR7006 Institut de Physique et Chimie des Matériaux de Strasbourg - IPCMS - UMR7504 |
| Langue |
en |
| Volume |
6 |
| Date de première publication |
2015 |
| ISSN |
2041-1723 |
| Titre de la source (revue, livre…) |
Nature Communications |
| Résumé |
The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties, such as lasing, room temperature polariton condensation and the modification of excited electronic landscapes involved in Show moreThe optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties, such as lasing, room temperature polariton condensation and the modification of excited electronic landscapes involved in molecular isomerization. Here we show that molecular vibrational modes of the electronic ground state can also be coherently coupled with a microcavity mode at room temperature, given the low vibrational thermal occupation factors associated with molecular vibrations, and the collective coupling of a large ensemble of molecules immersed within the cavity-mode volume. This enables the enhancement of the collective Rabi-exchange rate with respect to the single-oscillator coupling strength. The possibility of inducing large shifts in the vibrational frequency of selected molecular bonds should have immediate consequences for chemistry. Show less |
| DOI | 10.1038/ncomms6981 |
| Éditeur |
Nature Publishing Group |
| URL éditeur |
http://dx.doi.org/10.1038/ncomms6981 |
| Type de publication |
journal article |
| Type de publication |
ACL |
| Projet(s) de recherche ANR |
ANR-11-LABX-0058_NIE |
| Projet(s) de recherche européen(s) |
EC/FP7/227577///PLASMONICS |
| Topic |
Aucun |
| Équipes de recherche |
E1 - DON : Département d'optique ultra-rapide et nanophotonique |
| Fonction |
aut |
| Identifiant idREF |
185463894 075088843 086037536 |
| Audience |
Non spécifiée |
| URL | https://univoak.eu/islandora/object/islandora:60086 |