Modulating the Charge Transport in 2D Semiconductors via Energy‐Level Phototuning

Accès libre Peer reviewed | |
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Version acceptée pour publication (post-print auteur) | |
Paternité - Pas d'utilisation commerciale [CC] [BY] [NC] ![]() |
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Auteurs |
Haixin Qiu Yuda Zhao Zhaoyang Liu Martin Herder Stefan Hecht Paolo Samorì |
Unité de recherche du site |
Institut de Science et d'Ingénierie Supramoléculaires - ISIS - UMR7006 |
Langue |
en |
Volume |
31 |
Numéro |
39 |
Page de début |
1903402 |
Date de première publication |
2019-08-12 |
ISSN |
0935-9648 |
Titre de la source (revue, livre…) |
Advanced Materials |
Résumé |
The controlled functionalization of semiconducting 2D materials (2DMs) with photoresponsive molecules enables the generation of novel hybrid structures as active components for the fabrication of high‐performance multifunctional field‐effect Show moreThe controlled functionalization of semiconducting 2D materials (2DMs) with photoresponsive molecules enables the generation of novel hybrid structures as active components for the fabrication of high‐performance multifunctional field‐effect transistors (FETs) and memories. This study reports the realization of optically switchable FETs by decorating the surface of the semiconducting 2DMs such as WSe2 and black phosphorus with suitably designed diarylethene (DAE) molecules to modulate their electron and hole transport, respectively, without sacrificing their pristine electrical performance. The efficient and reversible photochemical isomerization of the DAEs between the open and the closed isomer, featuring different energy levels, makes it possible to generate photoswitchable charge trapping levels, resulting in the tuning of charge transport through the 2DMs by alternating illumination with UV and visible light. The device reveals excellent data‐retention capacity combined with multiple and well‐distinguished accessible current levels, paving the way for its use as an active element in multilevel memories. Show less |
DOI | 10.1002/adma.201903402 |
Titre abrégé de la source |
Adv. Mater. |
Type de publication |
ACL |
Domaine |
Chimie/Matériaux |
Unité de recherche extérieure au site |
Department of Chemistry and IRIS AdlershofHumboldt‐Universität zu Berlin 12489 Berlin Germany |
Fonction |
aut |
Identifiant idREF |
109288335 |
Audience |
International |
Envoyer vers HAL |
5 |
URL | https://univoak.eu/islandora/object/islandora:81420 |