Dynamic covalent conjugated polymer epitaxy on graphene

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ASSIES, Lea, FU, Chaoying, KOVAŘÍČEK, Petr, BASTL, Zdeněk, DROGOWSKA, Karolina A., LANG, Jan, GUERRA, Valentino L. P., SAMORÌ, Paolo, ORGIU, Emanuele, PEREPICHKA, Dmitrii F. et KALBÁČ, Martin, 2019. Dynamic covalent conjugated polymer epitaxy on graphene. Journal of Materials Chemistry C. 16 septembre 2019. Vol. 7, n° 39pp. 12240-12247. DOI 10.1039/C9TC03155C.
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Auteurs Lea Assies
Chaoying Fu
Petr Kovaříček
Zdeněk Bastl
Karolina A. Drogowska
Jan Lang
Valentino L. P. Guerra
Paolo Samorì
Emanuele Orgiu
Dmitrii F. Perepichka
Martin Kalbáč
Unité de recherche du site J. Heyrovsky Institute of Physical Chemistry of the Czech Academy of Sciences
University of Strasbourg
Department of Low Temperature Physics
INRS
Department of Chemistry
Langue

en
Volume

7
Numéro

39
Page de début

12240
Page de fin

12247
Date de première publication

2019-09-16
ISSN

2050-7526
2050-7534
Titre de la source (revue, livre…)

Journal of Materials Chemistry C
Résumé

Hybrid heterostructures formed from ordered molecular layers on two-dimensional materials can have unique properties differing from those of their bulk phases. By employing principles of dynamic covalent chemistry, we have synthesized a series of
Show moreHybrid heterostructures formed from ordered molecular layers on two-dimensional materials can have unique properties differing from those of their bulk phases. By employing principles of dynamic covalent chemistry, we have synthesized a series of novel conjugated polyimines that form epitaxial ordered monolayers on graphene. The interplay between molecular physisorption and dynamic polymerization at the solid–liquid interface drives the formation of longer chains at the surface with dramatically higher rates than in solution. The physico-chemical properties of such assemblies at different length scales on graphene were investigated by a combination of experimental techniques. ‘Covalent dynamic epitaxy’ was also found to modulate the properties of both substrate and dynamers such as doping and photoluminescence, respectively.
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DOI 10.1039/C9TC03155C
Titre abrégé de la source

J. Mater. Chem. C
Type de publication

ACL
Domaine

Chimie/Matériaux
Audience

International
Envoyer vers HAL

1
URL https://univoak.eu/islandora/object/islandora:83949