Phototuning Selectively Hole and Electron Transport in Optically Switchable Ambipolar Transistors

en

30

5

1908944

2019-12-04

1616-301X
1616-3028

Advanced Functional Materials

One of the grand challenges in organic electronics is to develop multicomponent materials wherein each component imparts a different and independently addressable property to the hybrid system. In this way, the combination of the pristine properties Show moreOne of the grand challenges in organic electronics is to develop multicomponent materials wherein each component imparts a different and independently addressable property to the hybrid system. In this way, the combination of the pristine properties of each component is not only preserved but also combined with unprecedented properties emerging from the mutual interaction between the components. Here for the first time, that tri‐component materials comprised of an ambipolar diketopyrrolopyrrole‐based semiconducting polymer combined with two different photochromic diarylethene molecules possessing ad hoc energy levels can be used to develop organic field‐effect transistors, in which the transport of both, holes and electrons, can be photo‐modulated. A fully reversible light‐switching process is demonstrated, with a light‐controlled 100‐fold modulation of p‐type charge transport and a tenfold modulation of n‐type charge transport. These findings pave the way for photo‐tunable inverters and ultimately for completely re‐addressable high‐performance circuits comprising optical storage units and ambipolar field‐effect transistors. Show less

Adv. Funct. Mater.

ACL

Chimie/Matériaux

King Abdullah University of Science and Technology (KAUST)Kaust Solar Center (KSC) Thuwal 23955–6900 Saudi Arabia
Department of Materials Science and EngineeringStanford University Stanford CA 94305 USA
Department of Chemistry and IRIS AdlershofHumboldt‐Universität zu Berlin Brook‐Taylor‐Str. 2 12489 Berlin Germany

aut

International

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